These apps work on android and apple phones (apart from peanut android only ) and any version of windows some applications also work on macs.
As they are for licensed radio amateurs only you must submit a copy of your ham licence to get registered.
Voip is ideal if you like to have long chats and like to get know your fellow hams around the world as the contacts are not affected by radio propagation and they are also useful if you are unable to put up big antennas to work dx
Given that there is now little or no activity on many vhf/uhf simplex and repeater frequencies Voip is a good place to find activity.
Today many HF contacts are very short just a quick signal report exchange and on to the next one.
Some of the rooms on Voip link out on RF crossing over to different modes dmr dstar p25 nxdn m17 fusion etc from analogue so you also do have to be registered for dstar and dmr to be carried over those networks.